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dc.contributor.authorDucreux, E.
dc.contributor.authorVispoel, B.
dc.contributor.authorGrouiez, B.
dc.contributor.authorGamache, R.R.
dc.contributor.authorLepère, M.
dc.contributor.authorRobert, S.
dc.contributor.authorRégalia, L.
dc.date2025
dc.date.accessioned2025-08-14T07:30:50Z
dc.date.available2025-08-14T07:30:50Z
dc.identifier.urihttps://orfeo.belnet.be/handle/internal/14136
dc.descriptionCollisional parameters of H2O with CO2 are currently missing from international spectroscopic databases, although they are essential for accurate modeling of water vapor in CO2-rich planetary atmospheres. In this study, high-resolution infrared spectra of H2O broadened by CO2 were recorded using a Fourier Transform Spectrometer in the 1.18 and 2.34 µm spectral regions. CO2-collisional parameters for selected H2O transitions were derived through a multispectrum fitting procedure employing both Voigt and quadratic speed-dependent Voigt profiles. Furthermore, calculations based on the semi-classical Complex Robert-Bonamy-Ma formalism were performed to estimate CO2-broadened half-widths, line shifts, and their temperature dependencies across various atmospheric transparency windows. It results in a strong agreement between theoretical predictions and experimental data. Finally, the shared calculated linelist, obtained for a wide range of transitions, can be directly applied to radiative transfer modeling of atmospheres primarily composed of carbon dioxide.
dc.languageeng
dc.titleMeasurements and calculations of H2O broadened by CO2 collisional parameters for planetary atmospheres
dc.typeArticle
dc.subject.frascatiPhysical sciences
dc.audienceScientific
dc.subject.freeHigh resolution infrared spectroscopy
dc.subject.freeComplex Robert-Bonamy-Ma calculations
dc.subject.freeLine shape parameters
dc.subject.freeWater vapor
dc.subject.freeCarbon dioxide
dc.subject.freePlanetary atmospheres
dc.source.titleJournal of Quantitative Spectroscopy and Radiative Transfer
dc.source.volume345
dc.source.pageA109576
Orfeo.peerreviewedYes
dc.identifier.doi10.1016/j.jqsrt.2025.109576
dc.identifier.url


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