A selected ion flow tube study of the reactions of H3O +, NO+ and O2 •+ with some oxygenated biogenic volatile organic compounds
| dc.contributor.author | Amelynck, C. | |
| dc.contributor.author | Schoon, N. | |
| dc.contributor.author | Kuppens, T. | |
| dc.contributor.author | Bultinck, P. | |
| dc.contributor.author | Arijs, E. | |
| dc.date | 2005 | |
| dc.date.accessioned | 2016-12-07T10:36:06Z | |
| dc.date.available | 2016-12-07T10:36:06Z | |
| dc.identifier.uri | https://orfeo.belnet.be/handle/internal/4621 | |
| dc.description | The rate constants and product ion distributions of the reactions of H 3O+, NO+ and O2 •+ with 2-methyl-3-buten-2-ol, cis-3-hexen-1-ol, cis-3-hexenyl acetate, 1,8-cineole, 6-methyl-5-hepten-2-one, camphor and linalool have been determined at 150 Pa and 297 K using a selected ion flow tube (SIFT). All reactions were found to proceed at a rate close to the collision rate, calculated with the Su and Chesnavich model, using the polarizability and electric dipole moment of the compounds derived from B3LYP/aug-cc-pVDZ quantum chemical calculations. Additionally the product ion distributions of the reactions of these three ions with the terpenoid alcohols nerol and geraniol have been obtained. | |
| dc.language | eng | |
| dc.title | A selected ion flow tube study of the reactions of H3O +, NO+ and O2 •+ with some oxygenated biogenic volatile organic compounds | |
| dc.type | Article | |
| dc.subject.frascati | Chemical sciences | |
| dc.audience | Scientific | |
| dc.source.title | International Journal of Mass Spectrometry | |
| dc.source.volume | 247 | |
| dc.source.issue | 1-3 | |
| dc.source.page | 1-9 | |
| Orfeo.peerreviewed | Yes | |
| dc.identifier.doi | 10.1016/j.ijms.2005.08.010 | |
| dc.identifier.scopus | 2-s2.0-28444452585 |
