Gas phase reactions of HNO3 with Cl-, Cl-H2O, and Cl-HCl, of Cl2 with Cl-H2O and Cl-HCl, and of HCl with Cl-H2O

dc.contributor.author	Amelynck, C.
dc.contributor.author	Arijs, E.
dc.contributor.author	Schoon, N.
dc.contributor.author	Van Bavel, A.-M.
dc.date	1998
dc.date.accessioned	2017-05-19T11:04:36Z
dc.date.available	2017-05-19T11:04:36Z
dc.identifier.uri	https://orfeo.belnet.be/handle/internal/5401
dc.description	This paper reports on the gas phase reactions of HNO3 with Cl-, Cl-H2O, and Cl-HCl, of Cl2 with Cl-H2O and Cl-HCl, and of HCl with Cl-H2O. Rate constants and product ions have been determined at room temperature and at low pressures (0.7-1.7 mb) by means of a flow tube reactor coupled to a quadrupole mass spectrometer. Apart from Cl-HCl + Cl2, all reactions proceed at the collision rate. The reaction mechanism for all reactions, except for Cl- + HNO3, seems to be ligand switching. The implication of the results on a chemical ionisation method for the in situ derivation of stratospheric nitric acid concentrations is discussed. (Int J Mass Spectrom 181 (1998) 113-121)
dc.language	eng
dc.title	Gas phase reactions of HNO3 with Cl-, Cl-H2O, and Cl-HCl, of Cl2 with Cl-H2O and Cl-HCl, and of HCl with Cl-H2O
dc.type	Article
dc.subject.frascati	Earth and related Environmental sciences
dc.audience	Scientific
dc.source.title	International Journal of Mass Spectrometry
dc.source.volume	181
dc.source.issue	1-3
dc.source.page	113-121
Orfeo.peerreviewed	Yes
dc.identifier.doi	10.1016/S1387-3806(98)14163-5
dc.identifier.scopus	2-s2.0-0346462798