Thermal Maturity Estimation of Carbonaceous Material from Proterozoic Organic-Walled Microfossil Assemblages (DR Congo, Mauritania and Australia) by Using Raman Spectroscopy
Authors
Baludikay, B.
François, C.
Sforna, MC.
Beghin, J.
Cornet, Y.
Storme, JY.
Fagel, N.
Fontaine, F.
Krooss, B.
Baudet, D.
Delvaux, D.
Javaux, E.
Discipline
Earth and related Environmental sciences
Subject
Geodynamics and mineral resources
Audience
Scientific
Date
2017Metadata
Show full item recordDescription
Three shallow marine sedimentary sequences with ages variying from late Mesoproterozoic to early Neoprotetozoic were investigated. These are Mbuji-Mayi Supergroup (DR Congo), Atar/El Mreïti Group (Mauritania) and Kanpa Formation (Australia) [1,2,3], each containing exquisitely preserved organic-walled microfossil assemblages. The varying color of organic material into a same sample, the thickness of microfossil walls as well as the lack of vitrinite macerals in proterozoic succession make irrelevant classical thermal maturity indicators used in palynological studies such as Thermal alteration index (TAI) or vitrinite reflectance (vRo%). Thus, we performed Raman spectroscopy on microfossils and amorphous organic matter in both isolated kerogen and thin sections. In both instance, we obtained the same results. Raman geothermometry [4] and temperature estimate based on Raman reflectance [5] indicates a low-grade thermal maturity (150 250°C). To validate this temperature range, kerogen pyrolysis (Rock-Eval) and Illite Cristallinity analyses wereperformed. Given that our results are consistent in all geological contexts under investigation, we propose Raman spectroscopy instead of TAI for thermal maturity estimation of proterozoic microfossil assemblages preserved in shales. [1] Baludikay et al. (2016) Prec. Res. 281, 166 184. [2] Beghin et al. (2017) Prec. Res. 291, 63 82. [3] Cornet et al. (in prep.). [4] Kouketsu et al. (2014) Island Arc 23, 33 50. [5] Liu et al. (2013) Chin. Sci. Bull. 58No.11, 1285 1298.
Citation
Baludikay, B.; François, C.; Sforna, MC.; Beghin, J.; Cornet, Y.; Storme, JY.; Fagel, N.; Fontaine, F.; Krooss, B.; Baudet, D.; Delvaux, D.; Javaux, E. (2017). Thermal Maturity Estimation of Carbonaceous Material from Proterozoic Organic-Walled Microfossil Assemblages (DR Congo, Mauritania and Australia) by Using Raman Spectroscopy. , Goldschmidt, Vol. abstracts, 221,Identifiers
Type
Article
Peer-Review
No
Language
eng