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    Pyrogenic HONO seen from space: insights from global IASI observations

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    Authors
    Franco, B.
    Clarisse, L.
    Theys, N.
    Hadji-Lazaro, J.
    Clerbaux, C.
    Coheur, P.
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    Discipline
    Earth and related Environmental sciences
    Audience
    Scientific
    Date
    2024
    Metadata
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    Description
    Nitrous acid (HONO) is a key atmospheric component, acting as a major source of the hydroxyl radical (OH), the primary oxidant in the Earth's atmosphere. However, understanding its spatial and temporal variability remains a significant challenge. Recent TROPOspheric Monitoring Instrument (TROPOMI)/Sentinel-5 Precursor (S5P) ultraviolet–visible (UV–Vis) measurements of fresh fire plumes shed light on the impact of global pyrogenic HONO emissions. Here, we leverage Infrared Atmospheric Sounding Interferometer (IASI)/MetOp's global infrared satellite measurements, complementing midday TROPOMI observations with morning and evening overpasses, to detect and retrieve pyrogenic HONO in 2007–2023. Employing a sensitive detection method, we identify HONO enhancements within concentrated fire plumes worldwide. Most detections are in the Northern Hemisphere (NH) mid- and high latitudes, where intense wildfires and high injection heights favour HONO detection. IASI's nighttime measurements yield 10-fold more HONO detections than daytime measurements, emphasizing HONO's extended lifetime in the absence of photolysis during the night. The annual detection count increases by at least 3–4 times throughout the IASI time series, mirroring the recent surge in intense wildfires at these latitudes. Additionally, we employ a neural-network-based algorithm for retrieving pyrogenic HONO total columns from IASI and compare them with TROPOMI in the same fire plumes. The results demonstrate TROPOMI's efficacy in capturing HONO enhancements in smaller fire plumes and in proximity to fire sources, while IASI's morning and evening overpasses enable HONO measurements further downwind, highlighting the survival of HONO or its secondary formation along long-range transport in smoke plumes.
    Citation
    Franco, B.; Clarisse, L.; Theys, N.; Hadji-Lazaro, J.; Clerbaux, C.; Coheur, P. (2024). Pyrogenic HONO seen from space: insights from global IASI observations. , Atmospheric Chemistry and Physics, Vol. 24, Issue 8, 4973-5007, DOI: 10.5194/acp-24-4973-2024.
    Identifiers
    uri: https://orfeo.belnet.be/handle/internal/13229
    doi: http://dx.doi.org/10.5194/acp-24-4973-2024
    url:
    Type
    Article
    Peer-Review
    Yes
    Language
    eng
    Links
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