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    Measurements of H2O broadened by CO2 line-shape parameters: Beyond the Voigt profile

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    Ducreux(2024a).pdf (1.613Mb)
    Authors
    Ducreux, É.
    Grouiez, B.
    Robert, S.
    Lepère, M.
    Vispoel, B.
    Gamache, R.R.
    Régalia, L.
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    Discipline
    Physical sciences
    Subject
    High resolution infrared spectroscopy
    Line shape parameters
    Water vapor
    Carbon dioxide
    Line profiles
    Planetary
    atmospheres
    Audience
    Scientific
    Date
    2024
    Metadata
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    Description
    H2O is an important molecule in the quest to better understand the evolution of solar system. In the study of Venus and Mars CO2-rich atmospheres (around 96 % of their composition) and because of the space instruments constant improvements, the planetary community needs spectroscopic data as accurate as possible. Continuing from our previous study [JQSRT 231, 126(2019)], new spectra of H2O perturbed by CO2 were measured with our new experimental set-up in the 2.7 µm region to compare with the previous results. After the improvement in the determination of the partial pressure of water vapor, the line parameters were then determined with a multispectrum fitting procedure using a Voigt profile in the same way as in [JQSRT 231, 126(2019)]. This led to characteristic W-shape residuals that have been improved using beyond-Voigt profiles. Our investigation showed that considering the speed dependence of collisional line parameters is essential to obtain better line-shape parameters in the considered experimental conditions.
    Citation
    Ducreux, É.; Grouiez, B.; Robert, S.; Lepère, M.; Vispoel, B.; Gamache, R.R.; Régalia, L. (2024). Measurements of H2O broadened by CO2 line-shape parameters: Beyond the Voigt profile. , Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 323, A109026, DOI: 10.1016/j.jqsrt.2024.109026.
    Identifiers
    uri: https://orfeo.belnet.be/handle/internal/13254
    doi: http://dx.doi.org/10.1016/j.jqsrt.2024.109026
    url:
    Type
    Article
    Peer-Review
    Yes
    Language
    eng
    Links
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