Characterisation of vertical BrO distribution during events of enhanced tropospheric BrO in Antarctica, from combined remote and in-situ measurements
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Authors
Roscoe, H.K.
Brough, N.
Jones, A.E.
Wittrock, F.
Richter, A.
Van Roozendael, M.
Hendrick, F.
Discipline
Earth and related Environmental sciences
Subject
Discrepancy
Halogens
Ozone
Troposphere
Audience
Scientific
Date
2014Metadata
Show full item recordDescription
Tropospheric BrO was measured by a ground-based remote-sensing spectrometer at Halley in Antarctica in spring 2007, and BrO was measured by satellite-borne remote-sensing spectrometers using similar spectral regions and similar Differential Optical Absorption Spectroscopy (DOAS) analyses. Near-surface BrO was simultaneously measured in situ at Halley by Chemical Ionisation Mass Spectrometer (CIMS), and in an earlier year near-surface BrO was measured at Halley over a long path by a ground-based DOAS spectrometer. During enhancement episodes, total amounts of tropospheric BrO from the ground-based remote-sensor were similar to those from space, but if we assume that the BrO was confined to the mixed layer they were very much larger than values measured by either near-surface technique. This large apparent discrepancy can be resolved if substantial amounts of BrO were in the free troposphere during most enhancement episodes. Amounts observed by the ground-based remote sensor at different elevation angles, and their formal inversions to vertical profiles, demonstrate that much of the BrO was indeed often in the free troposphere. This is consistent with the ~5 day lifetime of Bry and with the enhanced BrO observed during some Antarctic blizzards.
Citation
Roscoe, H.K.; Brough, N.; Jones, A.E.; Wittrock, F.; Richter, A.; Van Roozendael, M.; Hendrick, F. (2014). Characterisation of vertical BrO distribution during events of enhanced tropospheric BrO in Antarctica, from combined remote and in-situ measurements. , Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 138, 70-81, DOI: 10.1016/j.jqsrt.2014.01.026.Identifiers
scopus: 2-s2.0-84894470265
Type
Article
Peer-Review
Yes
Language
eng