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    Henry's law constants of polyols

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    Compernolle(2014a).pdf (741.2Kb)
    Authors
    Compernolle, S.
    Müller, J.-F.
    Discipline
    Chemical sciences
    Subject
    aerosol
    dilution
    hydroxyl radical
    solubility
    vapor pressure
    Audience
    Scientific
    Date
    2014
    Metadata
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    Description
    Henry's law constants (HLC) are derived for several polyols bearing between 2 and 6 hydroxyl groups, based on literature data for water activity, vapour pressure and/or solubility. While deriving HLC and depending on the case, also infinite dilution activity coefficients (IDACs), solid state vapour pressures or activity coefficient ratios are obtained as intermediate results. An error analysis on the intermediate quantities and the obtained HLC is included. For most compounds, these are the first values reported, while others compare favourably with literature data in most cases. Using these values and those from a previous work (Compernolle and Müller, 2014), an assessment is made on the partitioning of polyols, diacids and hydroxy acids to droplet and aqueous aerosol.
    Citation
    Compernolle, S.; Müller, J.-F. (2014). Henry's law constants of polyols. , Atmospheric Chemistry and Physics, Vol. 14, Issue 23, 12815-12837, DOI: 10.5194/acp-14-12815-2014.
    Identifiers
    uri: https://orfeo.belnet.be/handle/internal/2860
    doi: http://dx.doi.org/10.5194/acp-14-12815-2014
    scopus: 2-s2.0-84905383685
    Type
    Article
    Peer-Review
    Yes
    Language
    eng
    Links
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