Henry's law constants of polyols
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Authors
Compernolle, S.
Müller, J.-F.
Discipline
Chemical sciences
Subject
aerosol
dilution
hydroxyl radical
solubility
vapor pressure
Audience
Scientific
Date
2014Metadata
Show full item recordDescription
Henry's law constants (HLC) are derived for several polyols bearing between 2 and 6 hydroxyl groups, based on literature data for water activity, vapour pressure and/or solubility. While deriving HLC and depending on the case, also infinite dilution activity coefficients (IDACs), solid state vapour pressures or activity coefficient ratios are obtained as intermediate results. An error analysis on the intermediate quantities and the obtained HLC is included. For most compounds, these are the first values reported, while others compare favourably with literature data in most cases. Using these values and those from a previous work (Compernolle and Müller, 2014), an assessment is made on the partitioning of polyols, diacids and hydroxy acids to droplet and aqueous aerosol.
Citation
Compernolle, S.; Müller, J.-F. (2014). Henry's law constants of polyols. , Atmospheric Chemistry and Physics, Vol. 14, Issue 23, 12815-12837, DOI: 10.5194/acp-14-12815-2014.Identifiers
scopus: 2-s2.0-84905383685
Type
Article
Peer-Review
Yes
Language
eng