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    Estimating fusion properties for functionalised acids

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    Compernolle(2011b).pdf (328.2Kb)
    Authors
    Compernolle, S.
    Ceulemans, K.
    Muller, J.-F.
    Discipline
    Physical sciences
    Subject
    aerosol property
    enthalpy
    entropy
    error analysis
    organic acid
    partitioning
    sublimation
    vapor pressure
    Audience
    Scientific
    Date
    2011
    Metadata
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    Description
    Multicomponent organic aerosol (OA) is likely to be liquid, or partially liquid. Hence, to describe the partitioning of these components, their liquid vapour pressure is desired. Functionalised acids (e.g. diacids) can be a significant part of OA. But often measurements are available only for solid state vapour pressure, which can differ by orders of magnitude from their liquid counterparts. To convert such a sublimation pressure to a subcooled liquid vapour pressure, fusion properties (two out of these three quantities: fusion enthalpy, fusion entropy, fusion temperature) are required. Unfortunately, experimental knowledge of fusion properties is sometimes missing in part or completely, hence an estimation method is required. Several fusion data estimation methods are tested here against experimental data of functionalised acids, and a simple estimation method is developed, specifically for this family of compounds, with a significantly smaller estimation error than the literature methods.
    Citation
    Compernolle, S.; Ceulemans, K.; Muller, J.-F. (2011). Estimating fusion properties for functionalised acids. , Atmospheric Chemistry and Physics, Vol. 11, Issue 16, 8385-8394, DOI: 10.5194/acp-11-8385-2011.
    Identifiers
    uri: https://orfeo.belnet.be/handle/internal/3064
    doi: http://dx.doi.org/10.5194/acp-11-8385-2011
    scopus: 2-s2.0-80051736224
    Type
    Article
    Peer-Review
    Yes
    Language
    eng
    Links
    NewsHelpdeskBELSPO OA Policy

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