Global observations of tropospheric BrO columns using GOME-2 satellite data

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Authors
Theys, N.
Van Roozendael, M.
Hendrick, F.
Yang, X.
De Smedt, I.
Richter, A.
Begoin, M.
Errera, Q.
Johnston, P.V.
Kreher, K.
De Maziere, M.
Discipline
Earth and related Environmental sciences
Subject
aerosol
atmospheric chemistry
atmospheric plume
bromine
computer simulation
global perspective
GOME
ground-based measurement
ion
numerical model
observational method
polar region
quantitative analysis
SCIAMACHY
sea salt
stratosphere
tropopause
troposphere
Audience
Scientific
Date
2011Metadata
Show full item recordDescription
Measurements from the GOME-2 satellite instrument have been analyzed for tropospheric BrO using a residual technique that combines measured BrO columns and estimates of the stratospheric BrO content from a climatological approach driven by O3 and NO2 observations. Comparisons between the GOME-2 results and BrO vertical columns derived from correlative ground-based and SCIAMACHY nadir observations, present a good level of consistency. We show that the adopted technique enables separation of stratospheric and tropospheric fractions of the measured total BrO columns and allows quantitative study of the BrO plumes in polar regions. While some satellite observed plumes of enhanced BrO can be explained by stratospheric descending air, we show that most BrO hotspots are of tropospheric origin, although they are often associated to regions with low tropopause heights as well. Elaborating on simulations using the p-TOMCAT tropospheric chemical transport model, this result is found to be consistent with the mechanism of bromine release through sea salt aerosols production during blowing snow events. No definitive conclusion can be drawn however on the importance of blowing snow sources in comparison to other bromine release mechanisms. Outside polar regions, evidence is provided for a global tropospheric BrO background with column of 1–3 × 1013 molec cm−2, consistent with previous estimates.
Citation
Theys, N.; Van Roozendael, M.; Hendrick, F.; Yang, X.; De Smedt, I.; Richter, A.; Begoin, M.; Errera, Q.; Johnston, P.V.; Kreher, K.; De Maziere, M. (2011). Global observations of tropospheric BrO columns using GOME-2 satellite data. , Atmospheric Chemistry and Physics, Vol. 11, Issue 4, 1791-1811, DOI: 10.5194/acp-11-1791-2011.Identifiers
scopus: 2-s2.0-79952080505
Type
Article
Peer-Review
Yes
Language
eng