A global stratospheric bromine monoxide climatology based on the BASCOE chemical transport model
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Authors
Theys, N.
Van Roozendael, M.
Errera, Q.
Hendrick, F.
Daerden, F.
Chabrillat, S.
Dorf, M.
Pfeilsticker, K.
Rozanov, A.
Lotz, W.
Burrows, J.P.
Lambert, J.-C.
Goutail, F.
Roscoe, H.K.
De Mazière, M.
Discipline
Earth and related Environmental sciences
Subject
atmospheric chemistry
atmospheric dynamics
atmospheric transport
bromine compound
climatology
parameterization
photochemistry
stratosphere
Audience
Scientific
Date
2009Metadata
Show full item recordDescription
A new climatology of stratospheric BrO profiles based on a parameterization using dynamical and chemical indicators has been developed, with the aim to apply it to the retrieval of tropospheric BrO columns from space nadir measurements. The adopted parameterization is based on three years of output data from the 3-D chemistry transport model BASCOE. The impact of the atmospheric dynamics on the stratospheric BrO distribution is treated by means of Bry/ozone correlations built from 3-D-CTM model results, while photochemical effects are taken into account using stratospheric NO2 columns as an indicator of the BrO/Bry ratio. The model simulations have been optimized for bromine chemistry and budget, and validated through comparisons using an extensive data set of ground-based, balloon-borne and satellite limb (SCIAMACHY) stratospheric BrO observations.
Citation
Theys, N.; Van Roozendael, M.; Errera, Q.; Hendrick, F.; Daerden, F.; Chabrillat, S.; Dorf, M.; Pfeilsticker, K.; Rozanov, A.; Lotz, W.; Burrows, J.P.; Lambert, J.-C.; Goutail, F.; Roscoe, H.K.; De Mazière, M. (2009). A global stratospheric bromine monoxide climatology based on the BASCOE chemical transport model. , Atmospheric Chemistry and Physics, Vol. 9, Issue 3, 831-848,Type
Article
Peer-Review
Yes
Language
eng