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    Twelve years of global observations of formaldehyde in the troposphere using GOME and SCIAMACHY sensors

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    Authors
    De Smedt, I.
    Müller, J.-F.
    Stavrakou, T.
    Van Der A, R.
    Eskes, H.
    Van Roozendael, M.
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    Discipline
    Earth and related Environmental sciences
    Subject
    air mass
    albedo
    cloud
    comparative study
    data set
    Envisat-1
    formaldehyde
    GOME
    radiative transfer
    SCIAMACHY
    troposphere
    Audience
    Scientific
    Date
    2008
    Metadata
    Show full item record
    Description
    This work presents global tropospheric formaldehyde columns retrieved from near-UV radiance measurements performed by the GOME instrument onboard ERS-2 since 1995, and by SCIAMACHY, in operation on ENVISAT since the end of 2002. A special effort has been made to ensure the coherence and quality of the CH 2O dataset covering the period 1996-2007. Optimised DOAS settings are proposed in order to reduce the impact of two important sources of error in the derivation of slant columns, namely, the polarisation anomaly affecting the SCIAMACHY spectra around 350 nm, and a major absorption band of the O 4 collision complex centred near 360 nm. The air mass factors are determined from scattering weights generated using radiative transfer calculations taking into account the cloud fraction, the cloud height and the ground albedo. Vertical profile shapes of CH2O are provided by the global CTM IMAGES based on an up-to-date representation of emissions, atmospheric transport and photochemistry. A comprehensive error analysis is presented. This includes errors on the slant columns retrieval and errors on the air mass factors which are mainly due to uncertainties in the a priori profile and in the cloud properties. The major features of the retrieved formaldehyde column distribution are discussed and compared with previous CH2O datasets over the major emission regions.
    Citation
    De Smedt, I.; Müller, J.-F.; Stavrakou, T.; Van Der A, R.; Eskes, H.; Van Roozendael, M. (2008). Twelve years of global observations of formaldehyde in the troposphere using GOME and SCIAMACHY sensors. , Atmospheric Chemistry and Physics, Vol. 8, Issue 16, 4947-4963, DOI: 10.5194/acp-8-4947-2008.
    Identifiers
    uri: https://orfeo.belnet.be/handle/internal/4297
    doi: http://dx.doi.org/10.5194/acp-8-4947-2008
    scopus: 2-s2.0-50549098993
    Type
    Article
    Peer-Review
    Yes
    Language
    eng
    Links
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