• Login
     
    View Item 
    •   ORFEO Home
    • Royal Belgian Institute for Space Aeronomy
    • BIRA-IASB publications
    • View Item
    •   ORFEO Home
    • Royal Belgian Institute for Space Aeronomy
    • BIRA-IASB publications
    • View Item
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Validation of ACE-FTS v2.2 measurements of HCl, HF, CCl3F and CCl2F2 using space-, balloon- and ground-based instrument observations

    Thumbnail
    View/Open
    Mahieu(2008).pdf (1.631Mb)
    Authors
    Mahieu, E.
    Duchatelet, P.
    Demoulin, P.
    Walker, K.A.
    Dupuy, E.
    Froidevaux, L.
    Randall, C.
    Catoire, V.
    Strong, K.
    Boone, C.D.
    Bernath, P.F.
    Blavier, J.-F.
    Blumenstock, T.
    Coffey, M.
    De Mazière, M.
    Griffith, D.
    Hannigan, J.
    Hase, F.
    Jones, N.
    Jucks, K.W.
    Kagawa, A.
    Kasai, Y.
    Mebarki, Y.
    Mikuteit, S.
    Nassar, R.
    Notholt, J.
    Rinsland, C.P.
    Robert, C.
    Schrems, O.
    Senten, C.
    Smale, D.
    Taylor, J.
    Tétard, C.
    Toon, G.C.
    Warneke, T.
    Wood, S.W.
    Zander, R.
    Servais, C.
    Show allShow less
    Discipline
    Earth and related Environmental sciences
    Subject
    atmospheric chemistry
    atmospheric gas
    comparative study
    ground-based measurement
    observational method
    stratosphere
    twentieth century
    vortex
    winter
    Audience
    Scientific
    Date
    2008
    Metadata
    Show full item record
    Description
    Hydrogen chloride (HCl) and hydrogen fluoride (HF) are respectively the main chlorine and fluorine reservoirs in the Earth's stratosphere. Their buildup resulted from the intensive use of man-made halogenated source gases, in particular CFC-11 (CCl3F) and CFC-12 (CCl2F2), during the second half of the 20th century. It is important to continue monitoring the evolution of these source gases and reservoirs, in support of the Montreal Protocol and also indirectly of the Kyoto Protocol. The Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) is a space-based instrument that has been performing regular solar occultation measurements of over 30 atmospheric gases since early 2004. In this validation paper, the HCl, HF, CFC-11 and CFC-12 version 2.2 profile data products retrieved from ACE-FTS measurements are evaluated. Volume mixing ratio profiles have been compared to observations made from space by MLS and HALOE, and from stratospheric balloons by SPIRALE, FIRS-2 and Mark-IV. Partial columns derived from the ACE-FTS data were also compared to column measurements from ground-based Fourier transform instruments operated at 12 sites. ACE-FTS data recorded from March 2004 to August 2007 have been used for the comparisons. These data are representative of a variety of atmospheric and chemical situations, with sounded air masses extending from the winter vortex to summer sub-tropical conditions. Typically, the ACE-FTS products are available in the 10ĝ€"50 km altitude range for HCl and HF, and in the 7ĝ€"20 and 7ĝ€" 25 km ranges for CFC-11 and -12, respectively. For both reservoirs, comparison results indicate an agreement generally better than 5ĝ€"10% above 20 km altitude, when accounting for the known offset affecting HALOE measurements of HCl and HF. Larger positive differences are however found for comparisons with single profiles from FIRS-2 and SPIRALE. For CFCs, the few coincident measurements available suggest that the differences probably remain within ±20%.
    Citation
    Mahieu, E.; Duchatelet, P.; Demoulin, P.; Walker, K.A.; Dupuy, E.; Froidevaux, L.; Randall, C.; Catoire, V.; Strong, K.; Boone, C.D.; Bernath, P.F.; Blavier, J.-F.; Blumenstock, T.; Coffey, M.; De Mazière, M.; Griffith, D.; Hannigan, J.; Hase, F.; Jones, N.; Jucks, K.W.; Kagawa, A.; Kasai, Y.; Mebarki, Y.; Mikuteit, S.; Nassar, R.; Notholt, J.; Rinsland, C.P.; Robert, C.; Schrems, O.; Senten, C.; Smale, D.; Taylor, J.; Tétard, C.; Toon, G.C.; Warneke, T.; Wood, S.W.; Zander, R.; Servais, C. (2008). Validation of ACE-FTS v2.2 measurements of HCl, HF, CCl3F and CCl2F2 using space-, balloon- and ground-based instrument observations. , Atmospheric Chemistry and Physics, Vol. 8, Issue 20, 6199-6221, DOI: 10.5194/acp-8-6199-2008.
    Identifiers
    uri: https://orfeo.belnet.be/handle/internal/4300
    doi: http://dx.doi.org/10.5194/acp-8-6199-2008
    scopus: 2-s2.0-54949087550
    Type
    Article
    Peer-Review
    Yes
    Language
    eng
    Links
    NewsHelpdeskBELSPO OA Policy

    Browse

    All of ORFEOCommunities & CollectionsBy Issue DateAuthorsTitlesDisciplinesThis CollectionBy Issue DateAuthorsTitlesDisciplines
     

    DSpace software copyright © 2002-2016  DuraSpace
    Send Feedback | Cookie Information
    Theme by 
    Atmire NV