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    Evaluation of tropospheric and stratospheric ozone trends over Western Europe from ground-based FTIR network observations

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    Authors
    Vigouroux, C.
    De Mazière, M.
    Demoulin, P.
    Servais, C.
    Hase, F.
    Blumenstock, T.
    Kramer, I.
    Schneider, M.
    Mellqvist, J.
    Strandberg, A.
    Velazco, V.
    Notholt, J.
    Sussmann, R.
    Stremme, W.
    Rockmann, A.
    Gardiner, T.
    Coleman, M.
    Woods, P.
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    Discipline
    Earth and related Environmental sciences
    Subject
    atmospheric chemistry
    bootstrapping
    chemical composition
    comparative study
    FTIR spectroscopy
    greenhouse gas
    ground-based measurement
    optimization
    ozone
    stratosphere
    trend analysis
    troposphere
    Eurasia
    Europe
    Western Europe
    Audience
    Scientific
    Date
    2008
    Metadata
    Show full item record
    Description
    Within the European project UFTIR (Time series of Upper Free Troposphere observations from an European ground-based FTIR network), six ground-based stations in Western Europe, from 79deg; N to 28deg; N, all equipped with Fourier Transform infrared (FTIR) instruments and part of the Network for the Detection of Atmospheric Composition Change (NDACC), have joined their efforts to evaluate the trends of several direct and indirect greenhouse gases over the period 1995-2004. The retrievals of CO, CH4, C2H 6, N2O, CHClF2, and O3 have been optimized. Using the optimal estimation method, some vertical information can be obtained in addition to total column amounts. A bootstrap resampling method has been implemented to determine annual partial and total column trends for the target gases. The present work focuses on the ozone results. The retrieved time series of partial and total ozone columns are validated with ground-based correlative data (Brewer, Dobson, UV-Vis, ozonesondes, and Lidar). The observed total column ozone trends are in agreement with previous studies: 1) no total column ozone trend is seen at the lowest latitude station Izaña (28° N); 2) slightly positive total column trends are seen at the two mid-latitude stations Zugspitze and Jungfraujoch (47° N), only one of them being significant; 3) the highest latitude stations Harestua (60° N), Kiruna (68° N) and Ny-Ålesund (79° N) show significant positive total column trends. Following the vertical information contained in the ozone FTIR retrievals, we provide partial columns trends for the layers: ground-10 km, 10-18 km, 18-27 km, and 27-42 km, which helps to distinguish the contributions from dynamical and chemical changes on the total column ozone trends. We obtain no statistically significant trends in the ground-10 km layer for five out of the six ground-based stations. We find significant positive trends for the lowermost stratosphere at the two mid-latitude stations, and at Ny-Ålesund. We find smaller, but significant trends for the 18-27 km layer at Kiruna, Harestua, Jungfraujoch, and Izaña. The results for the upper layer are quite contrasted: we find significant positive trends at Kiruna, Harestua, and Jungfraujoch, and significant negative trends at Zugspitze and Izaña. These ozone partial columns trends are discussed and compared with previous studies.
    Citation
    Vigouroux, C.; De Mazière, M.; Demoulin, P.; Servais, C.; Hase, F.; Blumenstock, T.; Kramer, I.; Schneider, M.; Mellqvist, J.; Strandberg, A.; Velazco, V.; Notholt, J.; Sussmann, R.; Stremme, W.; Rockmann, A.; Gardiner, T.; Coleman, M.; Woods, P. (2008). Evaluation of tropospheric and stratospheric ozone trends over Western Europe from ground-based FTIR network observations. , Atmospheric Chemistry and Physics, Vol. 8, Issue 23, 6865-6886, DOI: 10.5194/acp-8-6865-2008.
    Identifiers
    uri: https://orfeo.belnet.be/handle/internal/4306
    doi: http://dx.doi.org/10.5194/acp-8-6865-2008
    scopus: 2-s2.0-57349148223
    Type
    Article
    Peer-Review
    Yes
    Language
    eng
    Links
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