• Login
     
    View Item 
    •   ORFEO Home
    • Royal Belgian Institute for Space Aeronomy
    • BIRA-IASB publications
    • View Item
    •   ORFEO Home
    • Royal Belgian Institute for Space Aeronomy
    • BIRA-IASB publications
    • View Item
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Analysis of the ν7+ν9 and 2ν7−ν9 band complexes of dicyanoacetylene (NC–CC–CN)

    View/Open
    Winther(2005).pdf (379.7Kb)
    Authors
    Winther, F.
    Horneman, V.-M.
    Vigouroux, C.
    Fayt, A.
    Show allShow less
    Discipline
    Chemical sciences
    Subject
    Acetylene
    Band structure
    Infrared spectroscopy
    Molecular dynamics
    Molecular vibrations
    Parameter estimation
    Resonance
    Band system
    Dicyanoacetulene
    Infrared gas spectrum
    Complexation
    Audience
    Scientific
    Date
    2005
    Metadata
    Show full item record
    Description
    The very weak ν7+ν9 band complex near 368 cm-1 and the 2ν70-ν9 system near 404 cm-1 in the infrared gas spectrum of dicyanoacetylene (NC-CC-CN) have been analysed. In the ν7+ν9 band system, we have assigned 68 subbands, reaching upper vibrational states with ν7 up to 3 and ν9 up to 8. The 11 subbands of the 2ν70-ν9 system with ν9 up to 7 could be observed because of intensity transfer from the ν3-ν9 band, a result of the strong anharmonic interaction between the ν3 and 2ν70 states. The combined data from the previously studied ν9 band together with the ν7+ν9 and 2ν7-ν9 bands were used for a global rovibrational analysis from which a full set of molecular parameters for the ν7 and ν9 modes has been deduced. A recently developed theory of intensities in such band systems has been applied to the ν7+ν9 band. Examples of intensity calculations illustrate some spectacular effects of the rotational and vibrational ℓ-type resonances on intensities. The observed intensities are in good agreement with the predicted values within the expected J-ranges.
    Citation
    Winther, F.; Horneman, V.-M.; Vigouroux, C.; Fayt, A. (2005). Analysis of the ν7+ν9 and 2ν7−ν9 band complexes of dicyanoacetylene (NC–CC–CN). , Journal of Molecular Structure, Vol. 742, Issue 1-3, 131-146, DOI: 10.1016/j.molstruc.2005.01.011.
    Identifiers
    uri: https://orfeo.belnet.be/handle/internal/4635
    doi: http://dx.doi.org/10.1016/j.molstruc.2005.01.011
    scopus: 2-s2.0-18144366612
    Type
    Article
    Peer-Review
    Yes
    Language
    eng
    Links
    NewsHelpdeskBELSPO OA Policy

    Browse

    All of ORFEOCommunities & CollectionsBy Issue DateAuthorsTitlesDisciplinesThis CollectionBy Issue DateAuthorsTitlesDisciplines
     

    DSpace software copyright © 2002-2016  DuraSpace
    Send Feedback | Cookie Information
    Theme by 
    Atmire NV