Line narrowing effect on the retrieval of HF and HCl vertical profiles from ground-based FTIR measurements
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Authors
Barret, B.
Hurtmans, D.
Carleer, M.R.
De Mazière, M.
Mahieu, E.
Coheur, P.-F.
Discipline
Earth and related Environmental sciences
Subject
Computer software
Earth atmosphere
Fourier transform infrared spectroscopy
Hydrogen inorganic compounds
Light absorption
Remote sensing
Solar radiation
Collision-induced line narrowing
SFIT2 software
Spectroscopic effect
Spectroscopic remote-sensing
Hydrochloric acid
atmospheric chemistry
spectroscopy
Audience
Scientific
Date
2005Metadata
Show full item recordDescription
Collision-induced line narrowing, which has been discovered in the 1950s and investigated thoroughly in the laboratory since then, has yet never been taken into account in the spectroscopic remote sensing of the atmosphere. This work investigates the effect of collision-induced line narrowing onto the retrieval of HCl and HF vertical profiles from ground-based solar absorption FTIR measurements made at the NDSC station of the Jungfraujoch (46.5°N, 8°E and 3580 m above see level). The retrievals are performed with the Atmosphit software, recently developed at the Université Libre de Bruxelles. It is presented in this paper for the first time and is validated against the widely used SFIT2 software. The impact of the line narrowing onto the retrieval of HCl and HF vertical profiles is examined relying on careful information content and error budget analyses. We report that the effect is relatively weak for HCl but significant for HF. Confirmation of the need to take the line narrowing into account for the retrieval of vertical profiles from ground-based FTIR spectra is given by comparison with data from the HALOE space borne instrument, rather insensitive to this spectroscopic effect.
Citation
Barret, B.; Hurtmans, D.; Carleer, M.R.; De Mazière, M.; Mahieu, E.; Coheur, P.-F. (2005). Line narrowing effect on the retrieval of HF and HCl vertical profiles from ground-based FTIR measurements. , Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 95, Issue 4, 499-519, DOI: 10.1016/j.jqsrt.2004.12.005.Identifiers
scopus: 2-s2.0-18844432324
Type
Article
Peer-Review
Yes
Language
eng