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    Absorption cross-sections of NO2: simulation of temperature and pressure effects

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    Vandaele(2003a).pdf (422.1Kb)
    Authors
    Vandaele, A.C.
    Hermans, C.
    Fally, S.
    Carleer, M.
    Mérienne, M.-F.
    Jenouvrier, A.
    Coquart, B.
    Colin, R.
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    Discipline
    Earth and related Environmental sciences
    Subject
    Adsorption
    Computer simulation
    Pressure effects
    Spectrum analysis
    Thermal effects
    Parameterization
    Nitrogen oxides
    adsorption
    air temperature
    atmospheric chemistry
    nitrogen dioxide
    pressure
    Audience
    Scientific
    Date
    2003
    Metadata
    Show full item record
    Description
    The measurements of the NO2 absorption cross sections by several authors have been considered in order to derive its temperature and pressure dependences in the 13 200-42 000 cm-1 spectral range. The temperature dependence is assumed to be linear in the temperature range investigated (217.0-298.5 K), whereas the influence of the total pressure is expressed as a temperature-dependent broadening coefficient. From measurements performed with mixtures of NO2 in air and in N2, values of γ0 air (296 K) and γ0 N2 (296 K) were found to be, respectively, 0.081 ± 0.002 and 0.069 ± 0.003 cm-1 atm-1. The temperature coefficient n obtained in the present work is 0.8 ± 0.1. The parameterization of the cross sections developed in this work can reproduce measured cross sections within 4%.
    Citation
    Vandaele, A.C.; Hermans, C.; Fally, S.; Carleer, M.; Mérienne, M.-F.; Jenouvrier, A.; Coquart, B.; Colin, R. (2003). Absorption cross-sections of NO2: simulation of temperature and pressure effects. , Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 76, Issue 3-4, 373-391, DOI: 10.1016/S0022-4073(02)00064-X.
    Identifiers
    uri: https://orfeo.belnet.be/handle/internal/5162
    doi: http://dx.doi.org/10.1016/S0022-4073(02)00064-X
    scopus: 2-s2.0-0037290875
    Type
    Article
    Peer-Review
    Yes
    Language
    eng
    Links
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