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    Gas phase reactions of negative ions with ClONO2

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    Amelynck(2001a).pdf (111.2Kb)
    Authors
    Amelynck, C.
    Stépien, C.
    Schoon, N.
    Catoire, V.
    Labonnette, D.
    Arijs, E.
    Poulet, G.
    Show allShow less
    Discipline
    Physical sciences
    Subject
    anion
    bromide
    carbonic acid
    chloride
    chlorine nitrate
    fluoride
    halide
    iodide
    nitrate
    nitric acid derivative
    nitric oxide
    unclassified drug
    apparatus
    article
    gas analysis
    ionization
    mass spectrometry
    precursor
    pressure
    reaction analysis
    stratosphere
    temperature
    Audience
    Scientific
    Date
    2001
    Metadata
    Show full item record
    Description
    The reactions of the halide anions (F-, Cl-, Br-, and I-), NO2-, SF6-, CO3- and CO4- with ClONO2 have been studied at room temperature in a flowing afterglow apparatus. All these reactions are found to proceed at the collision limit and the experimental data are compared with literature values. The reaction of I- with ClONO2 was studied at stratospheric pressures and temperatures in view of its use as a possible precursor ion for the measurement of stratospheric N2O5+ClONO2 mixing ratio height profiles by chemical ionization mass spectrometry. No pressure or temperature dependence of the rate constant has been observed. In order to correct the observed rate constants for HNO3 impurities, the reaction rate constants of F-, Br-, and NO2- with HNO3 have also been determined. In addition, the apparent second-order clustering rate constant of NO3- with ClONO2 in Ar/N2 and Ar/He mixtures has been measured.
    Citation
    Amelynck, C.; Stépien, C.; Schoon, N.; Catoire, V.; Labonnette, D.; Arijs, E.; Poulet, G. (2001). Gas phase reactions of negative ions with ClONO2. , International Journal of Mass Spectrometry, Vol. 207, Issue 3, 205-215, DOI: 10.1016/S1387-3806(01)00373-6.
    Identifiers
    uri: https://orfeo.belnet.be/handle/internal/5255
    doi: http://dx.doi.org/10.1016/S1387-3806(01)00373-6
    scopus: 2-s2.0-0035897562
    Type
    Article
    Peer-Review
    Yes
    Language
    eng
    Links
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