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    Slant column measurements of O3 and NO2 during the NDSC intercomparison of zenith-sky UV-visible spectrometers in June 1996

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    Roscoe(1999a).pdf (239.8Kb)
    Authors
    Roscoe, H.K.
    Johnston, P.V.
    Van Roozendael, M.
    Richter, A.
    Sarkissian, A.
    Roscoe, J.
    Preston, K.E.
    Lambert, J.-C.
    Hermans, C.
    Decuyper, W.
    Dzienus, S.
    Winterrath, T.
    Burrows, J.
    Goutail, F.
    Pommereau, J.-P.
    D'Almeida, E.
    Hottier, J.
    Coureul, C.
    Didier, R.
    Pundt, I.
    Bartlett, L.M.
    McElroy, C.T.
    Kerr, J.E.
    Elokhov, A.
    Giovanelli, G.
    Ravegnani, F.
    Premuda, M.
    Kostadinov, I.
    Erle, F.
    Wagner, T.
    Pfeilsticker, K.
    Kenntner, M.
    Marquard, L.C.
    Gil, M.
    Puentedura, O.
    Yela, M.
    Arlander, D.W.
    Kastad, Hoiskar, B.A.
    Tellefsen, C.W.
    Karlsen Tornkvist, K.
    Heese, B.
    Jones, R.L.
    Aliwell, S.R.
    Freshwater, R.A.
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    Discipline
    Earth and related Environmental sciences
    Subject
    nitrogen dioxide
    ozone
    nitrogen dioxide
    ozone
    air analysis
    article
    regression analysis
    reliability
    sensor
    spectrometer
    ultraviolet spectroscopy
    Audience
    Scientific
    Date
    1999
    Metadata
    Show full item record
    Description
    In June 1996, 16 UV-visible sensors from 11 institutes measured spectra of the zenith sky for more than 10 days. Spectra were analysed in real-time to determine slant column amounts of O3 and NO2. Spectra of Hg lamps and lasers were measured, and the amount of NO2 in a cell was determined by each spectrometer. Some spectra were re-analysed after obvious errors were found. Slant columns were compared in two ways: by examining regression analyses against comparison instruments over the whole range of solar zenith angles; and by taking fractional differences from a comparison instrument at solar zenith angles between 85°and 91°. Regression identified which pairs of instruments were most consistent, and so which could be used as universal comparison instruments. For O3, regression slopes for the whole campaign agreed within 5% for most instruments despite the use of different cross-sections and wavelength intervals, whereas similar agreement was only achieved for NO2 when the same cross-sections and wavelength intervals were used and only one half-day's data was analysed. Mean fractional differences in NO2 from a comparison instrument fall within ± 7% (1-sigma) for most instruments, with standard deviations of the mean differences averaging 4.5%. Mean differences in O3 fall within ± 2.5% (1-sigma) for most instruments, with standard deviations of the mean differences averaging 2%. Measurements of NO2 in the cell had similar agreement to measurements of NO2 in the atmosphere, but for some instruments measurements with cell and atmosphere relative to a comparison instrument disagreed by more than the error bars.
    Citation
    Roscoe, H.K.; Johnston, P.V.; Van Roozendael, M.; Richter, A.; Sarkissian, A.; Roscoe, J.; Preston, K.E.; Lambert, J.-C.; Hermans, C.; Decuyper, W.; Dzienus, S.; Winterrath, T.; Burrows, J.; Goutail, F.; Pommereau, J.-P.; D'Almeida, E.; Hottier, J.; Coureul, C.; Didier, R.; Pundt, I.; Bartlett, L.M.; McElroy, C.T.; Kerr, J.E.; Elokhov, A.; Giovanelli, G.; Ravegnani, F.; Premuda, M.; Kostadinov, I.; Erle, F.; Wagner, T.; Pfeilsticker, K.; Kenntner, M.; Marquard, L.C.; Gil, M.; Puentedura, O.; Yela, M.; Arlander, D.W.; Kastad, Hoiskar, B.A.; Tellefsen, C.W.; Karlsen Tornkvist, K.; Heese, B.; Jones, R.L.; Aliwell, S.R.; Freshwater, R.A. (1999). Slant column measurements of O3 and NO2 during the NDSC intercomparison of zenith-sky UV-visible spectrometers in June 1996. , Journal of Atmospheric Chemistry, Vol. 32, Issue 2, 281-314, DOI: 10.1023/A:1006111216966.
    Identifiers
    uri: https://orfeo.belnet.be/handle/internal/5367
    doi: http://dx.doi.org/10.1023/A:1006111216966
    scopus: 2-s2.0-0032992860
    Type
    Article
    Peer-Review
    Yes
    Language
    eng
    Links
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