Reactions of nitric acid with di- and trichloride ions, di- and tri-iodide ions and with CO- 4 in the gas phase
| dc.contributor.author | Amelynck, C. | |
| dc.contributor.author | Fussen, D. | |
| dc.contributor.author | Arijs, E. | |
| dc.date | 1994 | |
| dc.date.accessioned | 2017-06-01T11:16:15Z | |
| dc.date.available | 2017-06-01T11:16:15Z | |
| dc.identifier.uri | https://orfeo.belnet.be/handle/internal/5610 | |
| dc.description | The ion/molecule reactions of HNO3 with Cl- n and In - (n = 2,3) have been studied at room temperature by means of a flow tube coupled to a quadrupole mass spectrometer. The reaction rates for Cl- n + HNO3 for n = 2 and 3 have been determined relative to the known reaction rate for n = 1. Nitric acid reacts with Cl- 3, resulting mainly in the product ion NO- 3 · HCl. The product ion(s) of the slower two body reactions of Cl- 2 could not be determined unambiguously, but from thermodynamical considerations NO- 3 · HCl seems to be the most probable candidate. For the study of I- n + HNO3, the known reaction CO- 3 + HNO3 was used as a reference. No reaction has been observed for HNO3 with I- n ions (n = 2,3). Additionally, rate constants have been determined for the reactions of nitric acid with CO- 4, (NO3OH)-, (NO3HO2)- and NO- 3 · HCl. | |
| dc.language | eng | |
| dc.title | Reactions of nitric acid with di- and trichloride ions, di- and tri-iodide ions and with CO- 4 in the gas phase | |
| dc.type | Article | |
| dc.subject.frascati | Physical sciences | |
| dc.audience | Scientific | |
| dc.source.title | International Journal of Mass Spectrometry and Ion Processes | |
| dc.source.volume | 133 | |
| dc.source.issue | 1 | |
| dc.source.page | 13-28 | |
| Orfeo.peerreviewed | Yes | |
| dc.identifier.doi | 10.1016/0168-1176(94)03950-X | |
| dc.identifier.scopus | 2-s2.0-0002640908 |
