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    Reactions of nitric acid with di- and trichloride ions, di- and tri-iodide ions and with CO- 4 in the gas phase

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    Amelynck(1994a).pdf (1.075Mb)
    Authors
    Amelynck, C.
    Fussen, D.
    Arijs, E.
    Discipline
    Physical sciences
    Audience
    Scientific
    Date
    1994
    Metadata
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    Description
    The ion/molecule reactions of HNO3 with Cl- n and In - (n = 2,3) have been studied at room temperature by means of a flow tube coupled to a quadrupole mass spectrometer. The reaction rates for Cl- n + HNO3 for n = 2 and 3 have been determined relative to the known reaction rate for n = 1. Nitric acid reacts with Cl- 3, resulting mainly in the product ion NO- 3 · HCl. The product ion(s) of the slower two body reactions of Cl- 2 could not be determined unambiguously, but from thermodynamical considerations NO- 3 · HCl seems to be the most probable candidate. For the study of I- n + HNO3, the known reaction CO- 3 + HNO3 was used as a reference. No reaction has been observed for HNO3 with I- n ions (n = 2,3). Additionally, rate constants have been determined for the reactions of nitric acid with CO- 4, (NO3OH)-, (NO3HO2)- and NO- 3 · HCl.
    Citation
    Amelynck, C.; Fussen, D.; Arijs, E. (1994). Reactions of nitric acid with di- and trichloride ions, di- and tri-iodide ions and with CO- 4 in the gas phase. , International Journal of Mass Spectrometry and Ion Processes, Vol. 133, Issue 1, 13-28, DOI: 10.1016/0168-1176(94)03950-X.
    Identifiers
    uri: https://orfeo.belnet.be/handle/internal/5610
    doi: http://dx.doi.org/10.1016/0168-1176(94)03950-X
    scopus: 2-s2.0-0002640908
    Type
    Article
    Peer-Review
    Yes
    Language
    eng
    Links
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