Temperature-Dependence of Ultraviolet Absorption Cross-Sections of Alternative Chlorofluoroethanes
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Authors
Gillotay, D.
Simon, P.C.
Discipline
Earth and related Environmental sciences
Subject
chlorofluorohydrocarbon
air pollution
article
stratosphere
temperature
adsorption cross section
alternative hydrochlorofluoroethane
chlorofluoroethane
photodissociation coefficient
temperature dependence
ultraviolet absorption
Audience
Scientific
Date
1991Metadata
Show full item recordDescription
The absorption cross-sections of HCFC-123 (CF3-CHCl2), HCFC-141b (CH3-CFCl2) and HCFC-142b (CH3-CF2Cl) are measured between 170 and 250 nm for temperatures ranging from 295 to 210 K with uncertainties between 2 and 4%. They are compared with other available determinations. Temperature effects are discussed and parametrical formulae are proposed to compute the absorption cross-section for wavelengths and temperatures useful in atmospheric modelling calculations. Photodissociation coefficients are presented and their temperature-dependence is discussed.
Citation
Gillotay, D.; Simon, P.C. (1991). Temperature-Dependence of Ultraviolet Absorption Cross-Sections of Alternative Chlorofluoroethanes. , Journal of Atmospheric Chemistry, Vol. 12, Issue 3, 269-285, DOI: 10.1007/BF00048076.Identifiers
scopus: 2-s2.0-0025919407
Type
Article
Peer-Review
Yes
Language
eng