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    Ultraviolet absorption spectrum of trifluoro-bromo-methane, difluoro-dibromo-methane and difluoro-bromo-chloro-methane in the vapor phase

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    Authors
    Gillotay, D.
    Simon, P.C.
    Discipline
    Earth and related Environmental sciences
    Subject
    bromo- fluoro-methane
    difluoro- dibromo-methane
    difluoro-bromo-chloro-methane
    photodissociation coefficient
    trifluoro-bromo-methane
    ultraviolet absorption spectrum
    vapor phase
    bromochlorodifluoromethane
    bromotrifluoromethane
    dibromodifluoromethane
    photodissociation
    temperature dependence
    ultraviolet absorption spectrum
    Audience
    Scientific
    Date
    1989
    Metadata
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    Description
    Ultraviolet absorption cross-sections of trifluoro-bromo-methane (CF3Br-Halon 1301), difluoro-dibromo-methane (CF2Br2-Halon 1202) and of difluoro-bromo-chloro-methane (CF2BrCl-Halon 1211) are measured in the wavelength interval 172-304 nm for temperatures ranging from 210 to 295 K with uncertainties of between 2 and 4%. They are compared with previous measurements available at room temperature. Temperature effects are discussed and parametrical formulae are proposed to compute the absorption cross-sections for wavelengths and temperatures useful in atmospheric modelling calculations. Photodissociation coefficients are presented and their temperature dependence is discussed.
    Citation
    Gillotay, D.; Simon, P.C. (1989). Ultraviolet absorption spectrum of trifluoro-bromo-methane, difluoro-dibromo-methane and difluoro-bromo-chloro-methane in the vapor phase. , Journal of Atmospheric Chemistry, Vol. 8, Issue 1, 41-62, DOI: 10.1007/BF00053815.
    Identifiers
    uri: https://orfeo.belnet.be/handle/internal/5746
    doi: http://dx.doi.org/10.1007/BF00053815
    scopus: 2-s2.0-0024476726
    Type
    Article
    Peer-Review
    Yes
    Language
    eng
    Links
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