Ultraviolet absorption spectrum of trifluoro-bromo-methane, difluoro-dibromo-methane and difluoro-bromo-chloro-methane in the vapor phase
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Authors
Gillotay, D.
Simon, P.C.
Discipline
Earth and related Environmental sciences
Subject
bromo- fluoro-methane
difluoro- dibromo-methane
difluoro-bromo-chloro-methane
photodissociation coefficient
trifluoro-bromo-methane
ultraviolet absorption spectrum
vapor phase
bromochlorodifluoromethane
bromotrifluoromethane
dibromodifluoromethane
photodissociation
temperature dependence
ultraviolet absorption spectrum
Audience
Scientific
Date
1989Metadata
Show full item recordDescription
Ultraviolet absorption cross-sections of trifluoro-bromo-methane (CF3Br-Halon 1301), difluoro-dibromo-methane (CF2Br2-Halon 1202) and of difluoro-bromo-chloro-methane (CF2BrCl-Halon 1211) are measured in the wavelength interval 172-304 nm for temperatures ranging from 210 to 295 K with uncertainties of between 2 and 4%. They are compared with previous measurements available at room temperature. Temperature effects are discussed and parametrical formulae are proposed to compute the absorption cross-sections for wavelengths and temperatures useful in atmospheric modelling calculations. Photodissociation coefficients are presented and their temperature dependence is discussed.
Citation
Gillotay, D.; Simon, P.C. (1989). Ultraviolet absorption spectrum of trifluoro-bromo-methane, difluoro-dibromo-methane and difluoro-bromo-chloro-methane in the vapor phase. , Journal of Atmospheric Chemistry, Vol. 8, Issue 1, 41-62, DOI: 10.1007/BF00053815.Identifiers
scopus: 2-s2.0-0024476726
Type
Article
Peer-Review
Yes
Language
eng