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    Temperature dependence of ultraviolet absorption cross-sections of chlorofluoroethanes

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    Authors
    Simon, P.C.
    Gillotay, D.
    Vanlaethem-Meuree, N.
    Wisemberg, J.
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    Discipline
    Physical sciences
    Subject
    chlorofluoroethane
    haloethane
    temperature dependence
    ultraviolet absorption cross-section
    Audience
    Scientific
    Date
    1988
    Metadata
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    Description
    New absorption cross-sections of three haloethanes C 2F 5Cl, C 2F 4Cl 2 (CF 2Cl-CF 2Cl), and C 2F 3Cl 3 (CF 2 Cl-CFCl 2) measured between 172 and 250 nm for temperatures ranging from 225 to 295 K, are presented with uncertainties between 2 and 4%. They are compared with previous measurements available at room temperature and only at one low temperature, namely 208 K. The largest temperature effects which take place near the absorption threshold, can amount up to 50% for C 2F 3Cl 3 and 70% for C 2F 4Cl 2; temperature effect, if any, was too small to be detected in the case of C 2F 5Cl. Extrapolated values for temperatures of aeronomical interest are presented as well as parametrical formulae which give absorption cross-section values for given wavelength and temperature useful in stratospheric modelling calculations. Photodissociation coefficients are presented and their temperature dependence is discussed.
    Citation
    Simon, P.C.; Gillotay, D.; Vanlaethem-Meuree, N.; Wisemberg, J. (1988). Temperature dependence of ultraviolet absorption cross-sections of chlorofluoroethanes. , Annales Geophysicae, Vol. 6, Issue 3, 239-248,
    Identifiers
    uri: https://orfeo.belnet.be/handle/internal/5769
    scopus: 2-s2.0-0024220422
    Type
    Article
    Peer-Review
    Yes
    Language
    eng
    Links
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