Gas phase reactions of CF3O- and CF3O-·H2O and their relevance to the detection of stratospheric HCl
dc.contributor.author | Amelynck, C. | |
dc.contributor.author | Van, A.-M. | |
dc.contributor.author | Schoon, B.N. | |
dc.contributor.author | Arijs, E. | |
dc.date | 2000 | |
dc.date.accessioned | 2017-09-04T09:03:43Z | |
dc.date.available | 2017-09-04T09:03:43Z | |
dc.identifier.uri | https://orfeo.belnet.be/handle/internal/6121 | |
dc.description | The reactions of CF3O-, CF3O-·H2O and CF3O-·HF with HCl and of CF3O- with H2O have been studied at room temperature in a flowing afterglow instrument. All reactions with HCl proceed at the gas kinetic rate. The reaction of CF3O- with HCl proceeds by fluoride transfer, whereas CF3O-·H2O and CF3O-·HF react with HCl by ligand switching. The Gibbs free energy change of the reaction of CF3O- with H2O has been determined at room temperature as well as the collisional dissociation rate constant of CF3O-·H2O ions. | |
dc.language | eng | |
dc.title | Gas phase reactions of CF3O- and CF3O-·H2O and their relevance to the detection of stratospheric HCl | |
dc.type | Article | |
dc.audience | Scientific | |
dc.subject.free | carbon | |
dc.subject.free | fluoride | |
dc.subject.free | hydrochloric acid | |
dc.subject.free | water | |
dc.subject.free | article | |
dc.subject.free | chemical reaction kinetics | |
dc.subject.free | dissociation constant | |
dc.subject.free | gas | |
dc.subject.free | ionization | |
dc.subject.free | molecular interaction | |
dc.subject.free | reaction analysis | |
dc.subject.free | stratosphere | |
dc.subject.free | temperature | |
dc.source.title | International Journal of Mass Spectrometry | |
dc.source.volume | 202 | |
dc.source.issue | 1-3 | |
dc.source.page | 207-216 | |
Orfeo.peerreviewed | Yes | |
dc.identifier.doi | 10.1016/S1387-3806(00)00244-X | |
dc.identifier.scopus | 2-s2.0-0034675936 |