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dc.contributor.authorAmelynck, C.
dc.contributor.authorVan, A.-M.
dc.contributor.authorSchoon, B.N.
dc.contributor.authorArijs, E.
dc.date2000
dc.date.accessioned2017-09-04T09:03:43Z
dc.date.available2017-09-04T09:03:43Z
dc.identifier.urihttps://orfeo.belnet.be/handle/internal/6121
dc.descriptionThe reactions of CF3O-, CF3O-·H2O and CF3O-·HF with HCl and of CF3O- with H2O have been studied at room temperature in a flowing afterglow instrument. All reactions with HCl proceed at the gas kinetic rate. The reaction of CF3O- with HCl proceeds by fluoride transfer, whereas CF3O-·H2O and CF3O-·HF react with HCl by ligand switching. The Gibbs free energy change of the reaction of CF3O- with H2O has been determined at room temperature as well as the collisional dissociation rate constant of CF3O-·H2O ions.
dc.languageeng
dc.titleGas phase reactions of CF3O- and CF3O-·H2O and their relevance to the detection of stratospheric HCl
dc.typeArticle
dc.audienceScientific
dc.subject.freecarbon
dc.subject.freefluoride
dc.subject.freehydrochloric acid
dc.subject.freewater
dc.subject.freearticle
dc.subject.freechemical reaction kinetics
dc.subject.freedissociation constant
dc.subject.freegas
dc.subject.freeionization
dc.subject.freemolecular interaction
dc.subject.freereaction analysis
dc.subject.freestratosphere
dc.subject.freetemperature
dc.source.titleInternational Journal of Mass Spectrometry
dc.source.volume202
dc.source.issue1-3
dc.source.page207-216
Orfeo.peerreviewedYes
dc.identifier.doi10.1016/S1387-3806(00)00244-X
dc.identifier.scopus2-s2.0-0034675936


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