The near ultraviolet rotation-vibration spectrum of water
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Subject
Band structure
Electron transitions
Ground state
Light absorption
Molecular vibrations
Numerical methods
Rotation
Spectroscopic analysis
Ultraviolet radiation
Vapors
Excited vibrational states
Polyads
Vibration rotation transitions
Vibrational bands
Water vapor
Water
Audience
Scientific
Date
2000Metadata
Show full item recordDescription
A newly recorded, long pathlength, room temperature, rotation-vibration spectrum of water in the near-ultraviolet was analyzed using a newly computed ab initio linelist. Five new vibration bands of water were observed. It was found that one of each of these new states belongs to the previously unobserved 6ν + δ and 7ν + δ polyads, two belong to the 7ν polyad, and one to the 8ν polyad.
Citation
Zobov, N.F.; Belmiloud, D.; Polyansky, O.L.; Tennyson, J.; Shirin, S.V.; Carleer, M.; Jenouvrier, A.; Vandaele, A.-C.; Bernath, P.F.; Mérienne, M.F.; Colin, R. (2000). The near ultraviolet rotation-vibration spectrum of water. , Journal of Chemical Physics, Vol. 113, Issue 4, 1546-1552, DOI: 10.1063/1.481940.Identifiers
scopus: 2-s2.0-0034224769
Type
Article
Peer-Review
Yes
Language
eng