Fourier transform spectroscopy of the O2 Herzberg bands. II. Band oscillator strengths and transition moments

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Authors
Mérienne, M.-F.
Jenouvrier, A.
Coquart, B.
Carleer, M.
Fally, S.
Colin, R.
Vandaele, A.C.
Hermans, C.
Subject
Absorption spectroscopy
Dissociation
Electron energy levels
Electron transitions
Fourier transforms
Light absorption
Oxygen
Solar radiation
Spectrometers
Spectrum analysis
Band oscillator strengths
Fourier transform spectroscopy
Herzberg bands
Transition moments
Molecular spectroscopy
Audience
Scientific
Date
2000Metadata
Show full item recordDescription
From absorption spectra obtained at high resolution by coupling a Fourier transform spectrometer to a long-path multiple reflection cell the intensities of the O2 Herzberg bands (A3Σu+-X3Σg-, c1Σu-, A′ 3Δu-X3Σg-) have been studied at ambient temperature. The integrated cross section values are given for the lines of the (v′-0) bands in the A3ΣuPLU-X3Σg-, c1Σu--X3Σg-, and A′ 3Δu-X3Σg- transitions with v′ = 0-11, v′ = 2-19, and v′ = 2-12, respectively. The band oscillator strengths have been deduced and transition moments have been calculated. The total absorption values in the region of the Herzberg bands together with the photoabsorption values determined previously above the dissociation limit can be modeled by a single curve, in agreement with the continuity relationship of the cross sections through the dissociation limit.
Citation
Mérienne, M.-F.; Jenouvrier, A.; Coquart, B.; Carleer, M.; Fally, S.; Colin, R.; Vandaele, A.C.; Hermans, C. (2000). Fourier transform spectroscopy of the O2 Herzberg bands. II. Band oscillator strengths and transition moments. , Journal of molecular spectroscopy, Vol. 202, Issue 2, 171-193, DOI: 10.1006/jmsp.2000.8126.Identifiers
scopus: 2-s2.0-0343972354
Type
Article
Peer-Review
Yes
Language
eng