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    Diagnosing the Sensitivity of Particulate Nitrate to Precursor Emissions Using Satellite Observations of Ammonia and Nitrogen Dioxide

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    Authors
    Dang, R.
    Jacob, D.J.
    Zhai, S.
    Coheur, P.
    Clarisse, L.
    Van Damme, M.
    Pendergrass, D.C.
    Choi, J.-S.
    Park, J.
    S.
    Liu, Z.
    Liao, H.
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    Discipline
    Earth and related Environmental sciences
    Audience
    Scientific
    Date
    2023
    Metadata
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    Description
    Particulate nitrate is a major component of fine particulate matter (PM2.5). Its formation may be varyingly sensitive to emissions of ammonia (NH3), nitrogen oxides (NOx ≡ NO + NO2), and volatile organic compounds (VOCs), depending on local conditions. Diagnosing these sensitivities is critical for successful air quality management. Here, we show that satellite measurements of tropospheric NH3 and NO2 columns can be used as a quick indicator of the dominant sensitivity regime through the NH3/NO2 column ratio together with the NO2 column. We demonstrate the effectiveness of this indicator with the GEOS-Chem chemical transport model and define thresholds to separate the different sensitivity regimes. Applying the method to wintertime IASI and OMI observations in East Asia reveals that surface nitrate is dominantly VOC-sensitive in the southern North China Plain (NCP), NOx-sensitive in most of the East China Plain, and NH3-sensitive in the northern NCP, southern China, and Korea.
    Citation
    Dang, R.; Jacob, D.J.; Zhai, S.; Coheur, P.; Clarisse, L.; Van Damme, M.; Pendergrass, D.C.; Choi, J.-S.; Park, J.; S.; Liu, Z.; Liao, H. (2023). Diagnosing the Sensitivity of Particulate Nitrate to Precursor Emissions Using Satellite Observations of Ammonia and Nitrogen Dioxide. , Geophysical Research Letters, Vol. 50, Issue 24, e2023GL105761, DOI: 10.1029/2023GL105761.
    Identifiers
    uri: https://orfeo.belnet.be/handle/internal/11248
    doi: http://dx.doi.org/10.1029/2023GL105761
    url:
    Type
    Article
    Peer-Review
    Yes
    Language
    eng
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