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    Ultraviolet absorption cross-sections of chloro and chlorofluoro-methanes at stratospheric temperatures

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    Authors
    Simon, P.C.
    Gillotay, D.
    Vanlaethem-Meuree, N.
    Wisemberg, J.
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    Discipline
    Earth and related Environmental sciences
    Subject
    chlorofluorocarbon
    chlorofluoromethane
    chloromethane
    halomethane
    photodissociation coefficient
    ultraviolet absorption
    methyl chloride
    chlorofluoromethane
    photodissociation
    stratosphere
    temperature
    ultraviolet radiation
    Audience
    Scientific
    Date
    1988
    Metadata
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    Description
    Absorption cross-sections of nine halomethanes (CCl4, CHCl3, CH2Cl2, CH3Cl, CFCl3, CF2Cl2, CF3Cl, CHFCl2, and CHF2Cl), measured between 174 and 250 nm for temperatures ranging from 225 to 295 K, are presented with uncertainties ranging from 2 to 4% and compared with previous determinations made for comparable temperature ranges. The largest temperature effect which takes place near the absorption threshold, decreases the absorption cross-section up to 50% for highly chlorinated methanes, but is negligible for molecules highly stabilized by hydrogen and/or fluorine. Extrapolated values for temperatures of aeronomical interest are presented, as well as parametrical formulas which give absorption cross-section values for given wavelength and temperature ranges.
    Citation
    Simon, P.C.; Gillotay, D.; Vanlaethem-Meuree, N.; Wisemberg, J. (1988). Ultraviolet absorption cross-sections of chloro and chlorofluoro-methanes at stratospheric temperatures. , Journal of Atmospheric Chemistry, Vol. 7, Issue 2, 107-135, DOI: 10.1007/BF00048042.
    Identifiers
    uri: https://orfeo.belnet.be/handle/internal/5772
    doi: http://dx.doi.org/10.1007/BF00048042
    scopus: 2-s2.0-0023822447
    Type
    Article
    Peer-Review
    Yes
    Language
    eng
    Links
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