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    Thermodynamic field theory: chemical examples

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    Authors
    Peeters, P.H.
    Sonnino, G.
    Audience
    Scientific
    Date
    2000
    Metadata
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    Description
    The thermodynamic field theory. exposed in this issue. allows to describe thermodynamic systems. even when evolving far away from equilibrium. More particularly it is shown that far from equilibrium the tensor which relates forces with flows will display a skew-symmetric part. In this work we describe a simple chemical model characterised by the existence of a limit cycle (chemical oscillations). This model allows to compute the generalized flows taking into account Onsager's theory and by making an appropriate choice of fluxes and forces which leaves invariant the expression of the entropy production. We show that the numerical results are in agreement with the theoretical predictions.
    Citation
    Peeters, P.H.; Sonnino, G. (2000). Thermodynamic field theory: chemical examples. , Nuovo Cimento della Societa Italiana di Fisica B, Vol. 115, Issue 7-9, 1083-1090,
    Identifiers
    uri: https://orfeo.belnet.be/handle/internal/6134
    scopus: 2-s2.0-2242462303
    Type
    Article
    Peer-Review
    Yes
    Language
    eng
    Links
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