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    Long term changes in UT/LS ozone between the late 1970s and the 1990s deduced from GASP and MOZAIC aircraft programs and from ozonesondes.

    Authors
    Schnadt Poberaj, Ch.
    Stähelin, J.
    Brunner, D.
    Thouret, V.
    De Backer, H.
    Stübi, R.
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    Discipline
    Earth and related Environmental sciences
    Subject
    Natural sciences
    Earth and related Environmental sciences
    Audience
    General Public
    Scientific
    Date
    2009
    Publisher
    IRM
    KMI
    RMI
    Metadata
    Show full item record
    Description
    We present ozone measurements of the Global Atmospheric Sampling Program (GASP) performed from four commercial and one research aircraft in the late 1970s to compare them with respective measurements of the ongoing MOZAIC project. Multi-annual averages of UT/LS ozone were built using the aircraft data sets (1975–1979 and 1994–2001), and long term changes between the 1970s and 1990s were derived by comparison. The data were binned relative to the dynamical tropopause to separate between UT and LS air masses. LS data were analysed using equivalent latitudes. In the UT, pronounced increases of 20–40% are found over the Middle East and South Asia in the spring and summer seasons. Increases are also found over Japan, Europe, and the eastern parts of the United States depending on season. LS ozone over northern mid- and high latitudes was found to be lower in the 1990s compared to the 1970s in all seasons of the year. In addition, a comparison with long-term changes deduced from ozonesondes is presented. The early 1970s European Brewer-Mast (BM) sonde data agree with GASP within the range of uncertainty (UT) or measured slightly less ozone (LS). In contrast, the 1990s BM sensors show consistently and significantly higher UT/LS ozone values than MOZAIC. This unequal behaviour of aircraft/sonde comparisons in the 1970s and 1990s leads to differences in the estimated longterm changes over Europe: while the comparison between GASP and MOZAIC indicates ozone changes of −5% to10% over Europe, the sondes suggest a much larger increase of 10%–35% depending on station and season, although statistical significance is not conclusive due to data sample limitations. In contrast to the BM sondes, the Electrochemical Cell (ECC) sonde at Wallops Island, USA, measured higher UT ozone than both GASP and MOZAIC. Hence, long-term changes from GASP/MOZAIC agree within the range of uncertainty with the changes deduced from Wallops Island.
    Citation
    Schnadt Poberaj, Ch.; Stähelin, J.; Brunner, D.; Thouret, V.; De Backer, H.; Stübi, R. (2009). Long term changes in UT/LS ozone between the late 1970s and the 1990s deduced from GASP and MOZAIC aircraft programs and from ozonesondes.. , Issue Atmos. Chem. Phys., 9,, 5343-5369, IRM,
    Identifiers
    uri: https://orfeo.belnet.be/handle/internal/9179
    Type
    Article
    Peer-Review
    Yes
    Language
    eng
    Links
    NewsHelpdeskBELSPO OA Policy

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